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101.
Temperature Evolution of the Dielectric Response of α-Lactose Monohydrate in the THz Frequency Range
Komandin G. A. Porodinkov O. E. Nozdrin V. S. Musina G. R. Chernomyrdin N. V. Zaytsev K. I. Spektor I. E. 《Optics and Spectroscopy》2020,128(6):752-758
Optics and Spectroscopy - Transmission spectra of pressed microcrystalline α-lactose monohydrate samples have been measured by THz time-domain spectroscopy in the temperature range of... 相似文献
102.
Il’chuk G. A. Petrus’ R. Yu. Kashuba A. I. Semkiv I. V. Zmiiovs’ka E. O. 《Optics and Spectroscopy》2020,128(1):49-56
Optics and Spectroscopy - The results of experimental and theoretical studies of the optical and energy properties of thin CdSe films obtained by the quasi-closed volume method are presented. The... 相似文献
103.
104.
Russian Chemical Bulletin - Mechanisms of CO oxidation by oxygen in the PdBr2-LiBr-MeCN-H2O system in the absence and in the presence of iron(ii) phthalocyaninate (PcFe) as co-catalyst were studied... 相似文献
105.
Hossain M. A. Siddiki S. M. A. Hakim Elias M. Rahman M. M. Jamil M. A. R. 《Russian Journal of Organic Chemistry》2020,56(10):1806-1814
Russian Journal of Organic Chemistry - Methods have been reported for the preparation of ω-functionalized alkyl maltoside and glycoside detergents via a simple and inexpensive synthetic route.... 相似文献
106.
Vanessa R. Machado Louis P. Sandjo Giovanni L. Pinheiro Milene H. Moraes Mario Steindel Moacir G. Pizzolatti 《Natural product research》2018,32(3):275-281
The natural product lupeol 1 was isolated from aerial parts of Vernonia scorpioides with satisfactory yield, which made it viable to be used as starting material in semisynthetic approach. Ten lupeol derivatives 2–11 were prepared by classical procedures. Including, five new esters derivatives 7–11, which were obtained by structural modifications in the isopropylidene fragment. All semisynthetic compounds and lupeol 1–11 were confirmed by 1H NMR, 13C NMR and HRMS. Their antiprotozoal activity was evaluated in vitro against L. amazonensis and T. cruzi. Derivative 6 showed the best antitrypanosomal activity (IC50 = 12.48 μg/mL) and the lowest cytotoxic derivative (CC50 = 161.50 μg/mL). The mechanism of action of the most active derivatives (4, 6 and 11) is not dependent from the enzyme trypanothione reductase. 相似文献
107.
Laurens Kooijman Dr. Matthias Schuster Christian Baumann Simon Jurt Dr. Frank Löhr Dr. Boris Fürtig Prof. Dr. Peter Güntert Prof. Dr. Oliver Zerbe 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(47):21151-21158
To achieve efficient proton pumping in the light-driven proton pump bacteriorhodopsin (bR), the protein must be tightly coupled to the retinal to rapidly convert retinal isomerization into protein structural rearrangements. Methyl group dynamics of bR embedded in lipid nanodiscs were determined in the dark-adapted state, and were found to be mostly well ordered at the cytosolic side. Methyl groups in the M145A mutant of bR, which displays only 10 % residual proton pumping activity, are less well ordered, suggesting a link between side-chain dynamics on the cytosolic side of the bR cavity and proton pumping activity. In addition, slow conformational exchange, attributed to low frequency motions of aromatic rings, was indirectly observed for residues on the extracellular side of the bR cavity. This may be related to reorganization of the water network. These observations provide a detailed picture of previously undescribed equilibrium dynamics on different time scales for ground-state bR. 相似文献
108.
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Felix Unglaube Paul Hünemörder Xuewen Guo Zixu Chen Dengxu Wang Esteban Mejía 《Helvetica chimica acta》2020,103(12):e2000184
The redox activity of molecular phenazine catalysts has been previously exploited for aerobic oxidative amine homo- and cross-coupling reactions. In this contribution, we have extended the reaction scope of this novel type of organocatalyst and used them in the cross-dehydrogenative aza-Henry coupling of isoquinolines with nitromethane under aerobic conditions. Additionally, we have designed and prepared a novel porous organic polymer by cross-linking of tetrakis(4-bromophenyl)silane and dihydrophenazine through Pd-catalyzed Buchwald-Hartwig cross-coupling. This new type of heterogeneous catalyst, apart from being robust and easily reusable, also showed outstanding catalytic activities and improved selectivity compared to its molecular counterpart. A plausible reaction mechanism was proposed based on spectroscopic and kinetic measurements. 相似文献